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No, I agree with the table; it's chaotic neutral. She let the bandit go the first time!
She was distracted. And then she herself talked about how much she enjoys killing.Alignment
A chaotic evil character tends to have no respect for rules, other people's lives, or anything but their own desires, which are typically selfish and cruel. They set a high value on personal freedom, but do not have much regard for the lives or freedom of other people. Chaotic evil characters do not work well in groups because they resent being given orders and do not usually behave themselves unless there is no alternative.
This is literally Luna's behavior. Even when she thought she knew how to restore souls, she wasn't too concerned with the opinions of other characters. She wanted something, which meant they needed to be killed and bound to her forever.