The Dark Elves' only problem is mana, which is much less than that of the Academy of Magic or the High Elves.
First, I choose Iranna. She immediately gets Education (which is never a useless skill) along with Magic Affinity (which already gives 50% more mana at the start).
Second, the primary development task is to get Dark Ritual and Chaos Magic, which later leads to Chaos Lore, which gives +2 to Knowledge and a useful spell. Now you can survive – at least 45 mana (and possibly more, depending on level-ups and Education, if you're lucky).
By this time, you can also build a structure in the castle that gives another +1 to Knowledge.
In addition, Iranna has a bonus for Furies, which is always a plus, especially at the beginning...
The result is a great start with the fastest level-ups, an increased chance of getting a bonus to Knowledge, more Furies at the beginning, which are even stronger, and one and a half times more mana.