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#521
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Uranium235

We have 24 unidentified tanks left, as 2 out of 5 represents 10 possible outcomes.
We repeat the process. Here, 24 is divided by 3, resulting in 8. And 8 is divided by 2, resulting in 4. Accordingly, 2 units were taken from each tank again.
The first person drank from tanks 1-8, 9-12, and 17-20.
The second person drank from tanks 1-4, 9-16, and 21-24.
The third person drank from tanks 5-9, 13-16, and 17-24.
In total, we'll have to discard 4 tanks, but I can't think of a better solution. Or, we can experiment with the remaining survivors if they don't die within 12 hours.
I didn't understand this. After we do what you suggested earlier, we will have identified 12 tanks, one of which contains the poison (why 24 though??), three living subjects, and one attempt.

Added 2 minutes later
Ment seems to be right. It is indeed possible to determine the poison even in 243 barrels. I took 240 for a round number. I'll check again just in case.
Всё не так плохо как Вы думаете. Всё намного хуже!