I don't know exactly how he got it, or where. I played through the entire original game and Hammers of Fate, but I couldn't find it anywhere. And I still don't understand – in the last dialogue scene in Hammers of Fate, Biara sheds the guise of Isabel. What does Alaric do next?
Added 10 minutes later
Or Biara was a master of hypnosis, because appearing in the form of a succubus to the empire's chief "demon-fighter," even if he's a bit unhinged, is quite dangerous.