Medusa with a deadly gaze is a killer, especially if the hero has the Elven King's Bow and the "cat reaction" spell. It's simply a good fighter, and "terror" is a nice addition. As for Chaos Devils, no comment...
And if the hero also has "accuracy":D
Well, if we're talking about the topic, Ifrits + Chaos Devils + a bunch of heroes, mostly Chaos mages throwing fireballs, chokes, etc.:)
By the way, I think someone mentioned the high cost of building Chaos Devils somewhere; maybe I'm getting blind, or something changed in the same EC, but it seems like their lair still costs the same 14k + resources, and it's as "expensive" as any other dwelling:)
Added after 1 minute
(or even better when you have 2 castles and can take both)
And even better, 2 Chaos Devils per week:)

Барон "Vampires"
Отдай свои прошлые сны,
В сомненьях себя обрети,
В бешеном танце душа кружится!
Не думай, что будет потом,
Здесь и сейчас мы живем,
Стань хоть на миг сам собой, слышишь!